Synthetic Hydrogen-Bonding Receptors for Biologically Essential Monosaccharides

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Novel macrocyclic saccharide receptors that possess terpyridine skeletons as a hydrogen-bonding site are presented. On modification of the hydrogen-bonding sites and the macrocyclic bridges, the receptors showed selective bindings for ribofuranosides, deoxyribofuranosides, and glucopyranosides, respectively. The binding affinities of the receptors were very high, so that native monosaccharides were solubilized into non-polar solvents in the presence of the receptors. The hydrogen-bonding interactions and the binding modes between them were characterized by <SUP>1</SUP>H NMR spectroscopy.

収録刊行物

  • 有機合成化学協会誌

    有機合成化学協会誌 58(11), 1077-1083, 2000-11-01

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10008822231
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    ENG
  • 資料種別
    REV
  • ISSN
    00379980
  • NDL 記事登録ID
    5549715
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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