Organic Chemistry of Siloxane and Silanol.
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- Hirabayashi Kazunori
- Chemical Resources Laboratory, Tokyo Institute of Technology
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- Mori Atsunori
- Chemical Resources Laboratory, Tokyo Institute of Technology
Bibliographic Information
- Other Title
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- シロキサン・シラノールの有機化学
- シロキサン シラノール ノ ユウキ カガク
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Abstract
This article reviews organic chemistry of siloxane and silanol involving the preparative method as well as applications towards organic synthesis. Chapter 1 deals with the formation of siloxane bond and reactions of thus prepared siloxane compounds. Chapter 2 covers recent preparative methods for silanols and new synthetic reaction using silanol involving 1) utilization of silanol oxygen that serves as a base or a nucleophile, 2) transformation of neighboring functionality on the silicon substituent based on the interaction of silanol oxygen with an organometallic reagent, and 3) transformation of a carbon silicon bond of silanols directed to novel carbon-carbon bond forming reactions.
Journal
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- Journal of Synthetic Organic Chemistry, Japan
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Journal of Synthetic Organic Chemistry, Japan 58 (10), 926-933, 2000
The Society of Synthetic Organic Chemistry, Japan
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Keywords
Details 詳細情報について
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- CRID
- 1390001205278925312
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- NII Article ID
- 10008823905
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- NII Book ID
- AN0024521X
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- COI
- 1:CAS:528:DC%2BD3cXnsVKhurg%3D
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- ISSN
- 18836526
- 00379980
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- NDL BIB ID
- 5512262
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- Abstract License Flag
- Disallowed