The Formose Reaction on a Synthetic Zeolite Impregnated with Thiazolium Catalyst

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We investigated the formose reaction using a zeolite impregnated with thiazolium catalyst. The zeolite catalyzed the formose reaction in an organic solvent and then the reaction rate was pseudo first order with respect to the formaldehyde concentration. The main products were DHA, erythrulose, and 4-hydroxymethyl-2-pentulose. The selectivity of the branched sugar was increased by the choice of conditions. For the reuse of the catalytic zeolite, washing with water was one of the important factors. These results are important for sugar synthesis processes from formaldehyde in one step.

収録刊行物

  • Journal of chemical engineering of Japan

    Journal of chemical engineering of Japan 35(6), 564-568, 2002-06-01

    The Society of Chemical Engineers, Japan

参考文献:  8件中 1-8件 を表示

各種コード

  • NII論文ID(NAID)
    10008835271
  • NII書誌ID(NCID)
    AA00709658
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00219592
  • NDL 記事登録ID
    6183647
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-R395
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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