Modified Borohydride Agents, 1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane Tetrahydroborate (BAAOTB) versus Tetrabutylammonium Tetrahydroborate (TBATB). Efficient, Selective, and Versatile Reducing Agents

• Habib Firouzabadi

  Department of Chemistry, Shiraz UniversityShiraz 71454 , Iran

• Gholam Reza Afsharifar

  Department of Chemistry, Shiraz UniversityShiraz 71454 , Iran

抄録

1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane tetrahydroborate (BAAOTB) and tetrabutylammonium tetrahydroborate (TBATB) are used for the selective reductions of aldehydes, ketones, α,β-unsaturated carbonyl compounds, acid chlorides, azides, epoxides, and disulfides in t-BuOH and hexane/chloroform. ABBOAB with its rigid and bulky structure reacts more selectively than its analogue TBATB.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 68 (9), 2595-2602, 1995-09-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644034313472
• NII論文ID: 10008892947
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.68.2595
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/68/9/2595/56195760/bcsj.68.2595.pdf
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