Syntheses and Characterizations of Cyclotitanosiloxane and Cyclozirconosiloxane Compounds

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著者

    • GUNJI Takahiro
    • Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
    • KASAHARA Takayuki
    • Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
    • FUJII Akihiko
    • Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo
    • ABE Yoshimoto
    • Department of Industrial Chemistry, Faculty of Science and Technology, Science University of Tokyo

抄録

The syntheses and characterizations of cyclotitanosiloxane (CTS) and cyclozirconosiloxane (CZS) were investigated. CTS and CZS were synthesized by the reaction of di-<i>t</i>-butoxysilanediol with bis(acetylacetonato)diisopropoxidotitanium(IV) or bis(acetylacetonato)diisopropoxidozirconium(IV) in benzene. The formation of CTS and CZS was confirmed by the NMR and IR spectra and elemental analysis. The X-ray structural analysis for single crystals revealed that CTS and CZS consist of an eight-membered ring of two titano- or zirconosiloxane linkages bearing two <i>t</i>-butoxy groups on a silicon atom and two acetylacetonato groups on a titanium or zirconium atom.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 68(10), 2975-2979, 1995-10-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008894431
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • データ提供元
    CJP書誌  J-STAGE 
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