Allenyl(vinyl)methane Photochemistry. Photochemistry of 5-[2-(1,2-Propadienyl)-Substituted Alkylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones

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著者

    • TSUNO Takashi
    • Department of Industrial Chemistry, College of Industrial Technology, Nihon University
    • SUGIYAMA Kunio
    • Department of Industrial Chemistry, College of Industrial Technology, Nihon University

抄録

The Photochemistry of 5-[2-(1,2-propadienyl)-substituted alkylidene]-2,2-dimethyl-1,3-dioxane-4,6-diones has been studied. These acylals formed an intramolecular charge-transfer (CT) complex between the 1,2-propadienyl and vinyl moieties in acetonitrile and in hexane, the direct photolyses of which gave (1-alkenylidene)cyclopropanes as the main products, and the intramolecular [2+2] cycloadducts, 3-alkylidene-2′,2′,5,5-tetramethylspiro[bicyclo[2.1.0]pentane-2,5′-[1,3]dioxane]-4′,6′-diones as minor products. The (1-alkenylidene)cyclopropanes were produced from the enol intermediate via a preferred 1,5-hydrogen transfer of a diradical, which was formed via an intramolecular CT excited state. On the other hand, the acetone-sensitized photolyses afforded mainly the intramolecular [2+2] cycloadducts. It is considered that the lowest triplet energies of these acylals in acetonitrile were estimated to lie in the range of 250—290 kJ mol<sup>−1</sup>, and that these energies were near to the values of the reported triplet energies of <i>α</i>,<i>β</i>-unsaturated esters, because the allene underwent a [2+2] cycloaddition to the triplet vinyl moiety, excited by triplet sensitization.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 68(11), 3175-3188, 1995-11-15

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10008895185
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
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    CJP書誌  J-STAGE 
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