Valence Isomerism between Sterically Protected Methylenephosphine P-Sulfide and 1, 2-Thiaphosphirane

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著者

    • TOYOTA Kozo
    • Department of Chemistry, Graduate School of Science, Tohoku University
    • SHIMURA Kazuho
    • Department of Chemistry, Graduate School of Science, Tohoku University

抄録

Reaction of (diphenylmethylene)(2,4,6-tri-<i>t</i>-butylphenyl)phosphine with elemental sulfur afforded 3,3-diphenyl-2-(2,4,6-tri-<i>t</i>-butylphenyl)-1,2-thiaphosphirane 2-sulfide via methylenephosphine <i>P</i>-sulfide. Desulfurization reaction of the thiaphosphirane 2-sulfide with tris(dimethylamino)phosphine gave 3,3-diphenyl-2-(2,4,6-tri-<i>t</i>-butylphenyl)-1,2-thiaphosphirane. Valence isomerization occurred between the methylenephosphine <i>P</i>-sulfide and the thiaphosphirane by heat or by photo-irradiation. The structures of the methylenephosphine, the methylenephosphine <i>P</i>-sulfide, and the thiaphosphirane were analyzed by X-ray crystallography.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 69(1), 141-145, 1996-01-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008898522
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • データ提供元
    CJP書誌  J-STAGE 
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