Rh(I)-Catalyzed Dehydrogenative Silylation of Divinylsilanes with Dimethylphenylsilane

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著者

    • KAWANAMI Yukio
    • Department of Chemical Engineering, Tokyo Institute of Technology
    • YAMAMOTO Keiji
    • Department of Chemical Engineering, Tokyo Institute of Technology

抄録

Rh(I)-catalyzed dehydrogenative silylation was selectively carried out by using divinylsilanes and half an equimolar amount of trialkylsilanes under ambient conditions to give 1,2-disilylethene and ethylvinylsilane derivatives in equimolar amounts. The mechanistic aspects for the dehydrogenative silylation were discussed in terms of the consecutive migratory insertions of the alkene moiety into both Rh–Si and Rh–H bonds which are formed by an oxidative addition of the hydrosilane to the Rh(I) catalyst precursor.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 69(4), 1117-1124, 1996-04-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008902402
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • データ提供元
    CJP書誌  J-STAGE 
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