Preparations and Reactions of Functionalized Silyllithiums.

• Kawachi Atsushi

  Institute for Chemical Research, Kyoto University

• Tamao Kohei

  Institute for Chemical Research, Kyoto University

書誌事項

タイトル別名

• Preparations and Reactions of Functiona

抄録

Several types of α-alkoxy and α-amino substituted silyllithiums have been prepared as the first members of stable and/or well-characterizable functionalized silyllithiums. Described herein are new aspects of (1) three methodologies for preparation of functionalized silyllithiums, (2) high stability of (aminosilyl)lithiums, (3) low stability of (monoalkoxysilyl)lithiums, behaving as silylenoid species, (4) high stability of (dialkoxysilyl)lithiums, (5) high stability of (2-alkoxydisilanyl)lithium, (6) first examples of [2,3]-sila-Wittig rearrangement, and (7) synthetic utilization of (aminosilyl)lithiums.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 70 (5), 945-955, 1997

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204121570816
• NII論文ID: 130004058118
• NII論文ID: 10008918114
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.70.945
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 4219882
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4219882
• Web Site: https://academic.oup.com/bcsj/article-pdf/70/5/945/56199502/bcsj.70.945.pdf
• 本文言語コード: en
• データソース種別:
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