The Direct lodination of Arenes with Chromium(VI) Oxide as the Oxidant

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An easy and cheap laboratory method is presented for the direct mono- and diiodination of a number of activated and deactivated arenes. The main iodination reactions occurred at the temperatures not exceeding 65 °C for 0.5—12 h in the <i>anhydrous</i>, strongly acidic liquid system, I<sub>2</sub>/AcOH/Ac<sub>2</sub>O/H<sub>2</sub>SO<sub>4</sub>, in the presence of prior dissolved CrO<sub>3</sub> used as the oxidant. The yields of the pure iodinated products varied from 31% (for 3,5-diiodobenzoic acid) up to 90% (for 4-iodoanisole). So far, benzonitrile and some oxidizable aromatics, e.g. naphthalene, fluorene, xanthene, and thiophene, have been found to be unsuitable for the effective iodination. Nevertheless, this novel, simple method of direct iodination is worthy to be extended to other appropriate aromatics.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(7), 1665-1669, 1997-07-15

    The Chemical Society of Japan

参考文献:  22件中 1-22件 を表示

  • Formation of Carbon-Halogen Bonds (Cl, Br, I)

    SASSON Y.

    The Chemistry of Halides, Pseudo-Halides, and Azides, Supplement D1, 535-620, 1995

    被引用文献2件

  • Halobenzenes

    STEEL P. G.

    Rodd's Chem. Carbon Compd 3, 178-224, 1996

    被引用文献1件

  • <no title>

    FIESER L. F.

    Reagents for Organic Synthesis, 1968

    被引用文献1件

  • <no title>

    CAINELLI G.

    Chromium Oxidations in Organic Chemistry, 6-7, 1984

    被引用文献1件

  • <no title>

    SHIMIZU A.

    Bull. Chem. Soc. Jpn. 58, 1611, 1985

    被引用文献2件

  • <no title>

    GRIGOR'EV M. G.

    Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol 30, 22, 1987

    被引用文献2件

  • <no title>

    Chem. Abstr 109, 6142, 1988

    被引用文献1件

  • <no title>

    SERGUCHEV Yu. A.

    Ukr. Khim. Zh. (Russ. Ed. ) 59, 1159, 1993

    被引用文献1件

  • <no title>

    Chem. Abstr 121, 230015, 1994

    被引用文献1件

  • <no title>

    KAIMIERCZAK P.

    Communications at a Meeting of the Polish Chenmical Society, 1996

    被引用文献1件

  • <no title>

    OGATA Y.

    J. Am. Chem. Soc. 90, 6187, 1968

    被引用文献1件

  • <no title>

    KAZMIERCZAK P.

    Synthesis 1995, 1027

    被引用文献2件

  • <no title>

    Dictionary of Organic Compounds, 1996

    被引用文献4件

  • <no title>

    WILLGEROTH C.

    Justus Liebigs Ann. Chem. 389, 292, 1912

    被引用文献1件

  • <no title>

    BLAKEY W.

    J. Chem. Soc. 1927, 2865

    被引用文献1件

  • <no title>

    NOVIKOV A. N.

    Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 20, 1716, 1977

    被引用文献1件

  • <no title>

    Chem. Abstr 88, 89293, 1978

    被引用文献1件

  • <no title>

    LANGMUIR A. C.

    Ber. Dtsch. Chem. Ges. 28, 90, 1895

    被引用文献1件

  • <no title>

    BURCHFIELD H. P.

    Anal. Chem. 45, 916, 1973

    被引用文献1件

  • <no title>

    MERKUSHEV E. B.

    Synthesis 1988, 923

    DOI 被引用文献4件

  • <no title>

    KRASSOWSKA-SWIEBOCKA B.

    Synthesis 1995, 926

    DOI 被引用文献3件

  • <no title>

    MERKUSHEV E. B.

    Synthesis 1980, 486

    DOI 被引用文献3件

各種コード

  • NII論文ID(NAID)
    10008920823
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    4260306
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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