The First Structurally Characterized Salen-Indium Complexes

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In this manuscript are reported the synthesis and characterization of the first complexes of indium incorporating the acen and salen classes of ligands. This includes the compounds of formula LInMe (where L = acen (<b>1</b>) (<i>N</i>,<i>N</i>′-ethylenebis(2-hydroxy-<i>α</i>-methylbenzylidenimine)), salen (<b>2</b>) (<i>N</i>,<i>N</i>′-ethylenebis(2-hydroxybenzylideneimine)), salophen (<b>3</b>) (<i>N</i>,<i>N</i>′-(1,2-phenylene)bis(2-hydroxybenzylidenimine)), salomphen (<b>4</b>) (<i>N</i>,<i>N</i>′-(4,5-dimethyl-1,2-phenylene)bis(2-hydroxybenzylidenimine)). Attempts to prepare the derivatives, [In(R)(salpen)] (salpen = <i>N</i>,<i>N</i>′-propylenebis(2-hydroxybenzylidenimine), R = Me, Et) led to the formation of the bimetallic complexes, [(InMe<sub>2</sub>)<sub>2</sub>(salpen)] (<b>5</b>) and [In(Et<sub>2</sub>)<sub>2</sub>(salpen)] (<b>6</b>). Dissolution of <b>5</b> and <b>6</b> in MeOH causes the formation of three unusual products. They are the ligand bridged compounds [{In(<i>μ</i>-OMe)(<i>μ</i>-salpen)}<sub>2</sub>] (<b>7</b>), [{In(salpen)}<sub>2</sub>(<i>μ</i>-salpen)] (<b>8</b>) and the methoxy-only bridged complex, [{In(salpen)(<i>μ</i>-OMe)}<sub>2</sub>] (<b>9</b>). Compounds <b>7</b>—<b>9</b> are the first structurally characterized indium–salen complexes. For purposes of comparison, the structure of [{Al(salen)(<i>μ</i>-OMe)}<sub>2</sub>] (<b>10</b>) will also be described.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(9), 2093-2100, 1997-09-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008922680
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    4307567
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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