The First Structurally Characterized Salen-Indium Complexes
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- Other Title
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- First Structurally Characterized Salen-
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Abstract
<jats:title>Abstract</jats:title> <jats:p>In this manuscript are reported the synthesis and characterization of the first complexes of indium incorporating the acen and salen classes of ligands. This includes the compounds of formula LInMe (where L = acen (1) (N,N′-ethylenebis(2-hydroxy-α-methylbenzylidenimine)), salen (2) (N,N′-ethylenebis(2-hydroxybenzylideneimine)), salophen (3) (N,N′-(1,2-phenylene)bis(2-hydroxybenzylidenimine)), salomphen (4) (N,N′-(4,5-dimethyl-1,2-phenylene)bis(2-hydroxybenzylidenimine)). Attempts to prepare the derivatives, [In(R)(salpen)] (salpen = N,N′-propylenebis(2-hydroxybenzylidenimine), R = Me, Et) led to the formation of the bimetallic complexes, [(InMe2)2(salpen)] (5) and [In(Et2)2(salpen)] (6). Dissolution of 5 and 6 in MeOH causes the formation of three unusual products. They are the ligand bridged compounds [{In(μ-OMe)(μ-salpen)}2] (7), [{In(salpen)}2(μ-salpen)] (8) and the methoxy-only bridged complex, [{In(salpen)(μ-OMe)}2] (9). Compounds 7—9 are the first structurally characterized indium–salen complexes. For purposes of comparison, the structure of [{Al(salen)(μ-OMe)}2] (10) will also be described.</jats:p>
Journal
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 70 (9), 2093-2100, 1997-09
Tokyo : Chemical Society of Japan
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Details 詳細情報について
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- CRID
- 1521417755341973632
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- NII Article ID
- 10008922680
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- NII Book ID
- AA00580132
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- ISSN
- 00092673
- 13480634
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- NDL BIB ID
- 4307567
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- Text Lang
- en
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- NDL Source Classification
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- ZP1(科学技術--化学・化学工業)
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- Data Source
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- NDL
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- CiNii Articles