Imidazolyl-Tailed Tetrakis(pivalamidophenyl)porphyrinatocobalt (II) : An Efficient Oxygen Adsorbent Molecule

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A <i>meso</i>-tetrakis(<i>α</i>,<i>α</i>,<i>α</i>,<i>α</i>-<i>o</i>-pivalamidophenyl)porphyrinatocobalt(II) derivative bearing covalently-bound imidazole (Scheme 1, CoPim) was synthesized. Oxygen-binding to CoPim was rapid and reversible. The CoPim in the solid state chemically adsorbed oxygen (20 ml O<sub>2</sub>/g CoPim), which was ca. 40-times greater than the physical adsorption amount. The oxygen-binding lifetime of CoPim was longer than that for the corresponding porphyrinatocobalt(II) with an externally added imidazole. The efficiency of CoPim as an oxygen carrier was demonstrated by oxygen-enrichment from air using a pressure-swing adsorption experiment.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 70(9), 2317-2321, 1997-09-15

    The Chemical Society of Japan

参考文献:  13件中 1-13件 を表示

  • <no title>

    COLLMAN J. P.

    Acc. Chem. Res. 10, 265, 1977

    被引用文献10件

  • <no title>

    JONES R. D.

    Chem. Rev. 79, 139, 1979

    被引用文献9件

  • <no title>

    TSUCHIDA E.

    Top. Curr. Chem. 132, 64, 1986

    被引用文献9件

  • <no title>

    COLLMAN J. P.

    J. Am. Chem. Soc. 95, 7868, 1973

    被引用文献8件

  • <no title>

    TOSHIMA N.

    Polymers for Gas Separation, 1992

    被引用文献2件

  • <no title>

    TSUCHIDA E.

    Artificial Red Cells, 1995

    被引用文献2件

  • <no title>

    ESHIMA K.

    J. Chem. Soc., Chem. Commun. 1985, 130

    被引用文献1件

  • <no title>

    TSUCHIDA E.

    J.Chem.Soc., Perkin Trans 2 1995, 747

    被引用文献3件

  • <no title>

    COLLMAN J. P.

    J. Am. Chem. Soc. 97, 1427, 1975

    被引用文献12件

  • <no title>

    CALVIN M.

    J. Am. Chem. Soc. 68, 2254, 1946

    被引用文献2件

  • <no title>

    COLLMAN J. P.

    J. Am. Chem. Soc. 100, 2761, 1978

    被引用文献7件

  • <no title>

    COLLMAN J. P.

    J. Am. Chem. Soc. 102, 4182, 1980

    被引用文献10件

  • <no title>

    WHITE D. K.

    J. Am. Chem. Soc. 101, 2443, 1979

    被引用文献2件

各種コード

  • NII論文ID(NAID)
    10008923626
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    4307596
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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