Kinetics of Polymerization of Acrylamide in Aerosol OT W/O Microemulsions

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著者

    • KAWAI Takeshi
    • Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo
    • YASUDA Yoichi
    • Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo
    • KON-NO Kijiro
    • Department of Industrial Chemistry, Faculty of Engineering, Science University of Tokyo

抄録

Time dependence of the conversion of acrylamide (AAm) initiated with potassium peroxodisulfate (KPS) was examined at various [AAm] and [KPS] in W/O microemulsions of 1,4-bis(2-ethylhexyl) sodium sulfobutanedioate in cyclohexane media at 45 °C. The rate of polymerization (<i>R</i><sub>p</sub>) calculated from the conversion-time profiles yielded the following equation: <i>R</i><sub>p</sub> ∝ [AAm]<sup>1.0</sup>[KPS]<sup>0.5</sup>. From these values of reaction orders for AAm and KPS, it was found that the polymerization of acrylamide in W/O microemulsions can be regarded as normal radical polymerization and biradical termination between polymer radicals.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 68(8), 2175-2177, 1995-08-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10008940997
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • データ提供元
    CJP書誌  J-STAGE 
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