水晶振動子式センサによるｐｐｂレベルの石油留分ガスの検出

• 杉本 岩雄

  NTT入出力システム研究所

• 小川 茂樹

  NTT入出力システム研究所

• 中村 雅之

  NTT入出力システム研究所

• 瀬山 倫子

  NTT入出力システム研究所

• 加藤 忠

  NTT入出力システム研究所

書誌事項

タイトル別名

• Detection of Petroleum Gases at ppb Level Using Quartz Crystal Resonator Sensors.
• スイショウ シンドウシシキ センサ ニ ヨル ppb レベル ノ セキユリュウ

抄録

We have developed quartz crystal resonator (QCR) sensors coated with gas-sorption films produced by radio-frequency sputtering of porous sintered-polyethylene (PS-PE), polychlorotrifluoroethylene (PCTFE), and biomolecules including amino acids. We have measured the sensing capabilities of these sensors for vapors of gasoline, fuel oil, and their ingredients at ppb level. The sensing capabilities of PS-PE sensors were profoundly affected by the sputtering conditions; they were enhanced by the photo-excitation effect, and were reduced by carbonization and water treatment. The photo-excited PS-PE sensor was so sensitive that it could detect linear hydrocarbon (>C₁₂) vapors below the ppb level. The time constant of the sorption curve, however, was large, indicating a slow sensing speed. Amino-acid-film-coated sensors showed poor detection capabilities and PCTFE-film-coated sensor showed negligible sensing signals for the test vapors. The PS-PR film had higher affinities for organic vapors than for water vapor, and therefore is thought to be useful for environmental sensing.

収録刊行物

• 環境化学

  環境化学 8 (4), 831-840, 1998

  一般社団法人 日本環境化学会

キーワード

• Petroleum (Hydrocarbon) Gas Monitoring
• Quartz Crystal Resonator Sensor
• Plasma Polymer Film
• Polyethylene Film

詳細情報

• CRID: 1390282679347817216
• NII論文ID: 10009671781
• NII書誌ID: AN10547099
• DOI: 10.5985/jec.8.831
• ISSN: 18825818
• ISSN: 09172408
• NDL書誌ID: 4626829
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4626829
• Web Site: http://www.jstage.jst.go.jp/article/jec1991/8/4/8_4_831/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可