-
- KASEMURA Kazuo
- School of Chemistry and Environmental Technology, Faculty of Engineering, Kinki University
-
- FUJITA Shinji
- School of Chemistry and Environmental Technology, Faculty of Engineering, Kinki University
-
- OKADA Yoshiharu
- School of Chemistry and Environmental Technology, Faculty of Engineering, Kinki University
-
- FUJIHARA Yoshihito
- School of Chemistry and Environmental Technology, Faculty of Engineering, Kinki University
-
- NOMURA Masato
- School of Chemistry and Environmental Technology, Faculty of Engineering, Kinki University
書誌事項
- タイトル別名
-
- Miticidal Activity of Monoterpenyl Carboxypyrrolidinamides and Piperidinamides.
この論文をさがす
抄録
The monoterpene aldehydes, (-)-perillaaldehyde [1], (-)-myrtenal [2], were converted to nitriles by sequential N,N-dimethylhydrazonation, methylation and a Hofmann-type elimination reaction. The nitriles were subsequently converted to terpenoyl chlorides by hydroysis and chlorination with thionyl chloride. The chlorocarbonylated terpenes were condensed with pyrrolidine, 2-, 3-, or 4-methylpiperidines, and 2,6- or 3,5-dimethylpiperidines to produce 14 terpeneamides [1a]-[2g] in 42-87% overall yields in four steps starting with imidation of the terpene aldehydes. 1-Adamantanecarboxylic acid [3] and 1-adamantaneacetic acid [4] were condensed with pyrrolidine, 2-, 3-, or 4-methylpiperidines, and 2,6- or 3,5-dimethylpiperidines to afford 14 adamantane amides [3a]-[4g] in 41-90% overall yields in one step starting from adamantane derivatives. Miticidal activity of amide compounds [1a]-[4g] toward Tyrophagus putrescentiae and Dermatophagoides farinae was assessed. On filter paper, amide compounds [2a]-[2g] from [2] showed miticidal activity exceeding that of N,N-Dimethyl-m-toluamide (DEET) toward T. putrescentiae. On filter paper amide compounds [1c]-[1e] from [1] and [2a]-[2g] from [2] and showed [3b], [3d], [3e] from [3] and [4a], [4b], [4d], [4f], [4g] from [4] indicated greater miticidal activity compared to DEET for D. farinae.<br>
収録刊行物
-
- Journal of Oleo Science
-
Journal of Oleo Science 52 (1), 41-46, 2003
公益社団法人 日本油化学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204091570432
-
- NII論文ID
- 10010227982
-
- NII書誌ID
- AA11503337
-
- COI
- 1:CAS:528:DC%2BD3sXhslen
-
- ISSN
- 13473352
- 13458957
-
- NDL書誌ID
- 6402895
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可