M-DNA: A Self-Assembling Molecular Wire for Nanoelectronics and Biosensing.
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- WETTIG Shawn D.
- Department of Biochemistry, University of Saskatchewan
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- LI Chen-Zhong
- Department of Biochemistry, University of Saskatchewan Department of Chemistry, University of Saskatchewan
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- LONG Yi-Tao
- Department of Biochemistry, University of Saskatchewan Department of Chemistry, University of Saskatchewan
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- KRAATZ Heinz-Bernhard
- Department of Biochemistry, University of Saskatchewan Department of Chemistry, University of Saskatchewan
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- LEE Jeremy S.
- Department of Biochemistry, University of Saskatchewan
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M-DNA is a complex between divalent metal ions such as Zn2+ and duplex DNA which forms at pH 8.5. Unlike B-DNA, M-DNA does not bind ethidium so that M-DNA formation can be monitored conveniently by an ethidium fluorescence assay. M-DNA was shown to be a better conductor than B-DNA by fluorometric measurements of electron transport in donor-acceptor labelled duplexes; by direct conductivity measurements of M-DNA bound between gold electrodes and by cyclic voltammetric studies on ferrocene labelled duplexes attached to gold microelectrodes. As is the case with B-DNA, M-DNA can self-assemble into a variety of structures and is anticipated to find widespread use in nanoelectronics and biosensing.
収録刊行物
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- Analytical Sciences
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Analytical Sciences 19 (1), 23-26, 2003
社団法人 日本分析化学会
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詳細情報 詳細情報について
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- CRID
- 1390282679234719104
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- NII論文ID
- 10011102677
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- NII書誌ID
- AA10500785
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- ISSN
- 13482246
- 09106340
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- NDL書誌ID
- 6408766
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- PubMed
- 12558018
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- PubMed
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