Mechanically Induced Solid-State Reaction for Synthesizing New Multicomponent Ta<SUB>55</SUB>Zr<SUB>10</SUB>Ni<SUB>10</SUB>Al<SUB>10</SUB>Cu<SUB>15</SUB> Glassy Alloy Powders with Extremely Wide Supercooled Liquid Region

• El-Eskandarany M. Sherif

  Inoue SuperLiquid Glass Project, Exploratory Research for Advanced Technology,Japan Science and Technology Corporation

• Zhang Wei

  Inoue SuperLiquid Glass Project, Exploratory Research for Advanced Technology,Japan Science and Technology Corporation

• Inoue Akihisa

  Institute for Materials Research, Tohoku University

Bibliographic Information

Other Title

• Mechanically Induced Solid-State Reaction for Synthesizing New Multicomponent Ta55Zr10Ni10Al10Cu15 Glassy Alloy Powders with Extremely Wide Supercooled Liquid Region

Abstract

New multicomponent Ta-based glassy alloy powder was synthesized by mechanical alloying a mixture of elemental Ta₅₅Zr₁₀Ni₁₀Al₁₀Cu₁₅ powders at room temperature, using a low-energy ball mill. The glassy powders of the final-product (1080 ks) in which its glass transition temperature (T_g) lies at a high temperature (834 K), crystallize through a single sharp exothermic peak at 1004 K (T_x). The total enthalpy change of crystallization (ΔH_x) is −10.32 kJ/mol. The supercooled liquid region before crystallization (ΔT_x) of the synthesized glassy powder shows the widest value (170 K) of any reported metallic glassy system.

Journal

• MATERIALS TRANSACTIONS

  MATERIALS TRANSACTIONS 43 (6), 1422-1425, 2002

  The Japan Institute of Metals and Materials

Keywords

• ball milling
• mechanical alloying
• solid-state reaction; multicomponent metallic glassy material
• X-ray diffraction
• transmission electron microscope
• scanning electron microscope
• thermal stability

Details

• CRID: 1390282679228361472
• NII Article ID: 10012324653
• NII Book ID: AA1151294X
• DOI: 10.2320/matertrans.43.1422
• COI: 1:CAS:528:DC%2BD38Xls1Siurc%3D
• ISSN: 13475320
• ISSN: 13459678
• NDL BIB ID: 6200932
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I6200932
• Web Site: https://www.jstage.jst.go.jp/article/matertrans/43/6/43_6_1422/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed