Vapour Pressure Determination for Dibenzo-p-dioxin, Dibenzofuran, Octachlorodibenzo-p-dioxin and Octachlorodibenzofuran Using a Knudsen Effusion Method

  • Li Xian-Wei
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University
  • Shibata Etsuro
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University
  • Kasai Eiki
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University
  • Nakamura Takashi
    Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University

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抄録

A new apparatus with Knudsen effusion method especially designed for the vapour pressure measurements of dioxin congeners and other POPs is described. Crystalline benzoic acid and anthracene were first used to test the new designed apparatus. The vapour pressure and enthalpy results of the two reference compounds were found in good agreement with accepted literature data. The vapour pressure and enthalpy results of crystalline DD, DF, OCDD and OCDF determined with the new apparatus are presented, and compared with the literature data measured with other methods.

収録刊行物

  • MATERIALS TRANSACTIONS

    MATERIALS TRANSACTIONS 43 (11), 2903-2907, 2002

    公益社団法人 日本金属学会

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