Self-initiated Chain-growth Polycondensation for Aromatic Polyamides

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The polycondensation of phenyl 4-(octylamino)benzoate (<B>1</B>) proceeded in a chain-polymerization manner to yield aromatic polyamides with low polydispersities (<I>M</I><SUB>w</SUB>/<I>M</I><SUB>n</SUB> ≤ 1.1) even under normal conditions for step-growth polycondensation, in which initiator was not added. On the basis of the results of the polycondesations of <B>1</B> with initiator models, this self-initiated chain-growth polycondensation involves the formation of the dimer of <B>1</B>, which initiates the chain-growth polymerization faster than step-growth polymerization.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(3), 272-273, 2004-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012722740
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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