Lewis Base Catalyzed Michael Reaction between Ketene Silyl Acetals and α,β-Unsaturated Carbonyl Compounds

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  • Teruaki Mukaiyama
    The Kitasato Institute, Center for Basic Research, TCI6-15-5 Toshima, Kita-ku, Tokyo
  • Takashi Nakagawa
    The Kitasato Institute, Center for Basic Research, TCI6-15-5 Toshima, Kita-ku, Tokyo
  • Hidehiko Fujisawa
    The Kitasato Institute, Center for Basic Research, TCI6-15-5 Toshima, Kita-ku, Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Catalytic Michael reaction between trimethylsilyl enolates and α,β-unsaturated carbonyl compounds by using a Lewis base such as lithium benzamide or lithium succimide in a DMF solvent proceeded smoothly to afford the corresponding Michael adducts.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 32 (1), 56-57, 2002-12-20

    Oxford University Press (OUP)

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