Electrocatalytic Activation of Organosulfur Redox Reactions by Metal Nanoparticles

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  • Jong-Eun Park
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and TechnologyNaka-cho, Koganei, Tokyo
  • Osamu Hatozaki
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and TechnologyNaka-cho, Koganei, Tokyo
  • Noboru Oyama
    Department of Applied Chemistry, Faculty of Technology, Tokyo University of Agriculture and TechnologyNaka-cho, Koganei, Tokyo

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<jats:title>Abstract</jats:title> <jats:p>The effect of Ag nanoparticles on the redox reactions of organosulfur compounds was investigated. Adding the nanoparticles to 2,5-dimercapto-1,3,4-thiadiazole (DMcT)-polyaniline composites, redox activity of the composites was enhanced due to electrocatalytic activation of DMcT by the nanoparticles. It was expected that adsorption of DMcT to the nanoparticles would make a positive contribution to the electrocatalysis.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 32 (2), 138-139, 2003-01-17

    Oxford University Press (OUP)

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