1, 4-Addition of Diethylzinc to Cyclohexenone Catalyzed by CuOTf-Sulfonamide Combined System. Evidence Supporting a Concerted Mechanism

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著者

    • NAKANO Keiji
    • Contribution from the Research Center for Materials Science and Department of Chemistry, Nagoya University
    • BESSHO Yuhki
    • Contribution from the Research Center for Materials Science and Department of Chemistry, Nagoya University
    • KITAMURA Masato
    • Contribution from the Research Center for Materials Science and Department of Chemistry, Nagoya University

抄録

Measurement of <SUP>12</SUP>C/<SUP>13</SUP>C isotope effect in the Cu(I)/sulfonamide-catalyzed 1,4-addition of diethylzinc to 2-cyclohexenone implies that the reaction proceeds by a concerted mechanism, different to those so far reported for the conventional stoichiometric 1,4-addition of organometallic compounds involving Cu.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(3), 224-225, 2003-03-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012814458
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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