New Morphology-controlled Poly(aniline) Synthesis Using Anionic Porphyrin Aggregate as a Template

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著者

    • HATANO Tsukasa
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • TAKEUCHI Masayuki
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • IKEDA Atsushi
    • Graduate School of Materials Science, Nara Institute of Science and Technology
    • SHINKAI Seiji
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

抄録

It was found that 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS), which is known to aggregate in a one-dimensional direction in water, acted as a template for electrochemical polymerization of aniline on ITO electrode. Examinations using cyclic voltammetry (CV) and UV–vis spectroscopy established that J-aggregated TPPS molecules were entrapped in the resultant poly(aniline). Scanning electron microscopy (SEM) observation established that poly(aniline) grew up to a nanosized rod-like structure, reflecting the aggregation structure of TPPS. It is a very novel and important finding that poly(aniline), which has been believed to result in only "rigid" film, can be morphologically controlled using a "template method".

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 314-315, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012815234
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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