Chiral Recognition with Crown Ethers Having Planar Chiral (η^4-Diene)tricarbonyliron Moieties

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著者

    • YAMAGUCHI Hiroshi
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University
    • NAKANISHI Saburo
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University
    • KIHARA Nobuhiro
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University
    • TAKATA Toshikazu
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

抄録

Crown ethers with a planar chiral (1,3-η<SUP>4</SUP>-diene)tricarbonyliron unit were prepared. They revealed a good chiral recognition ability for α-substituted benzylammonium salts (<I>K</I><SUB><I>rel</I></SUB> = 1.3–2.0). Ligand substitution of the iron tricarbonyl moiety with triphenylphosphane inverted the chiral selectivity.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 410-411, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012816024
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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