[2. 0. 2. 0]Metacyclophane-1, 15-diynes. A Potential Fragment of Double-Helical Conjugated Systems

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著者

    • KAWASE Takeshi
    • Department of Chemistry, Graduate School of Science, Osaka University
    • ODA Masaji
    • Department of Chemistry, Graduate School of Science, Osaka University

抄録

The title cyclophanes as a potential fragment of double-helical π-conjugated system were synthesized, and the spectroscopic and crystallographic characterization shows the strained nature of the π-system; variable-temperature NMR spectra also reveal that the cyclophanes exist as an equilibrium mixture between the <I>meso</I>- and <I>dl</I>-forms in solution.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(4), 412-413, 2003-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012816045
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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