Novel Cerium(III)-(R)-BNP Complex as a Storable Chiral Lewis Acid Catalyst for the Enantioselective Hetero-Diels-Alder Reaction

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著者

    • HAYANO Tetsuji
    • Institute for Materials Chemistry and Engineering (IMCE), Kyushu University
    • FURUNO Hiroshi
    • Institute for Materials Chemistry and Engineering (IMCE), Kyushu University
    • OHBA Masaaki
    • Department of Chemistry, Faculty of Sciences, Kyushu University
    • OKAWA Hisashi
    • Department of Chemistry, Faculty of Sciences, Kyushu University
    • INANAGA Junji
    • Institute for Materials Chemistry and Engineering (IMCE), Kyushu University

抄録

A novel Ce(III)–(<I>R</I>)-BNP complex was conveniently prepared from CAN and (<I>R</I>)-BNP–Na, then successfully used as a homogeneous catalyst for the asymmetric hetero-Diels–Alder reaction affording, after acidic work-up, 6-substituted 5,6-dihydro-4<I>H</I>-pyran-4-one derivatives with high enantioselectivities (up to 94% ee). A mechanistically interesting positive nonlinear effect was also observed.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(7), 608-609, 2003-07-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012817511
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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