The Reaction of Metallothionein-3 with DTNB

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著者

    • ZHENG Qi
    • Chemical Biology Laboratory, Department of Chemistry, Fudan University
    • CAI Bin
    • Chemical Biology Laboratory, Department of Chemistry, Fudan University
    • CHEN Dong
    • Chemical Biology Laboratory, Department of Chemistry, Fudan University
    • YU Wen-Hao
    • Chemical Biology Laboratory, Department of Chemistry, Fudan University
    • WANG Yun-Hua
    • Chemical Biology Laboratory, Department of Chemistry, Fudan University

抄録

MT3 reacts with DTNB by a biphasic process, which roots from the difference in reactions between two domains with DTNB. The β-domain reacts with DTNB faster, implying that the CPCP motif distorts the peptide and leads to the Cd<SUB>3</SUB>S<SUB>9</SUB> cluster more accessible to solvent. This reaction is a S<SUB>N</SUB>2 process according to the activation entropy.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(7), 616-617, 2003-07-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012817587
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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