Efficient Photocycloreversion Reaction of Diarylethenes by Introduction of Cyano Subsutituents to the Reactive Carbons

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著者

    • MORIMITSU Kentaro
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • KOBATAKE Seiya
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
    • IRIE Masahiro
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University

抄録

Highly efficient photocycloreversion reaction was observed for diarylethene derivatives with cyano groups at the reactive carbons of the thiophene rings. The cycloreversion quantum yield of 1,2-bis(2-cyano-5-phenyl-3-thienyl)perfluorocyclopentene was found to be ca. 30 times larger than that of 1,2-bis(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene.

収録刊行物

  • Chemistry letters

    Chemistry letters 32(9), 858-859, 2003-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012819546
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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