Novel Selective Oxidation of Light Alkanes Using Carbon Dioxide. Oxidized Diamond as a Novel Catalytic Medium

  • Kiyoharu Nakagawa
    National Institute for Materials Science (NIMS)1-1 Namiki, Ibaraki
  • Kimito Okumura
    Department of Chemical Engineering and High Technology Research Center, Kansai UniversityOsaka
  • Takahiro Shimamura
    Department of Chemical Engineering and High Technology Research Center, Kansai UniversityOsaka
  • Na-oki Ikenaga
    Department of Chemical Engineering and High Technology Research Center, Kansai UniversityOsaka
  • Toshimitsu Suzuki
    Department of Chemical Engineering and High Technology Research Center, Kansai UniversityOsaka
  • Tetsuhiko Kobayashi
    Special Division for Green Life Technology, National Institute of Advanced Industrial Science and Technology (AIST)Osaka
  • Mikka Nishitani-Gamo
    Institute of Applied Physics and Center for Tsukuba Advanced Research Alliance (TARA), University of TsukubaIbaraki
  • Toshihiro Ando
    Core Research for Evolutional Science and Technology (CREST) of Japan Science and Technology Corporation (JST), NIMS1-1 Namiki, Ibaraki

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Abstract

<jats:title>Abstract</jats:title> <jats:p>Carbon dioxide is an effective oxidant for the conversion of alkanes to chemical feedstocks. Oxidized diamond is useful as a novel catalytic support material. Oxidized diamond provided catalytic sites for the activation of alkanes under CO2 atmosphere. The present findings also suggest that the surface-properties of oxidized diamond may facilitate unique catalytic reactions, such as alkanes conversion in the presence of CO2.</jats:p>

Journal

  • Chemistry Letters

    Chemistry Letters 32 (9), 866-867, 2003-08-25

    Oxford University Press (OUP)

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