Rhodium-Catalyzed Acylation of Vinylsilanes with Acid Anhydrides : Application to the Transformation of α-Acyloxy Vinylsilanes to Unsymmetrical 1, 2-Diketones

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著者

    • YAMANO Motoki
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • UERA Kazuyoshi
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • NARASAKA Koichi
    • Department of Chemistry, Graduate School of Science, The University of Tokyo

抄録

Acylation of vinylsilanes with acid anhydrides is catalyzed by [RhCl(CO)<SUB>2</SUB>]<SUB>2</SUB> to give α,β-unsaturated ketones. The application of this catalytic system to the acylation of α-acyloxy vinylsilanes affords α-acyloxy enones in good yields, which are converted to unsymmetrical 1,2-diketones or their mono acetals.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(4), 424-425, 2004-04-05

    The Chemical Society of Japan

参考文献:  17件中 1-17件 を表示

  • <no title>

    FLEMING I.

    Chem. Commun. 633, 1975

    被引用文献1件

  • <no title>

    COOKE F.

    J. Org. Chem. 45, 1046, 1980

    被引用文献3件

  • <no title>

    SASAKI T.

    J. Org. Chem. 47, 3219, 1982

    被引用文献2件

  • <no title>

    YAMANE M.

    Chem. Lett. 1210, 2001

    被引用文献1件

  • <no title>

    HIYAMA T.

    Top. Curr. Chem. 219, 61, 2002

    被引用文献4件

  • <no title>

    DENMARK S. E.

    J. Am. Chem. Soc. 121, 5821, 1999

    被引用文献4件

  • <no title>

    DENMARK S. E.

    Org. Lett. 2, 565, 2000

    被引用文献5件

  • <no title>

    KOIKE T.

    Angew. Chem., Int. Ed. 42, 89, 2003

    被引用文献4件

  • <no title>

    OI S.

    Org. Lett. 4, 667, 2002

    被引用文献5件

  • <no title>

    DENMARK S. E.

    J. Am. Chem. Soc. 123, 6439, 2001

    被引用文献4件

  • <no title>

    HIRABAYASHI K.

    J. Org. Chem. 65, 5342, 2000

    被引用文献7件

  • <no title>

    OGUMA K.

    J. Organomet. Chem. 648, 297, 2002

    被引用文献3件

  • <no title>

    HONDA M.

    Tetarahedron 58, 6815, 2002

    被引用文献2件

  • <no title>

    FRISTAD W. E.

    Tetrahedron Lett. 1999, 1979

    被引用文献1件

  • <no title>

    TUBUL A.

    Tetrahedron 44, 3975, 1988

    DOI 被引用文献2件

  • <no title>

    ITAMI K.

    J. Am. Chem. Soc. 123, 11577-11585, 2001

    DOI 被引用文献12件

  • <no title>

    FROST C. G.

    Chem. Commun. 2316, 2001

    被引用文献1件

各種コード

  • NII論文ID(NAID)
    10012847146
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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