Synthesis and Characterization of the First Organically Templated Layered Cerium Phosphate Fluoride : [(CH_2)_2(NH_3)_2]_<0.5>[Ce^<IV>F_3(HPO_4)]

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著者

    • YU Ranbo
    • Institute for Chemical Research, Kyoto University
    • WANG Dan
    • Institute of Process Engineering, Chinese Academy of Sciences
    • CHEN Yunfa
    • Institute of Process Engineering, Chinese Academy of Sciences
    • LI Jinghai
    • Institute of Process Engineering, Chinese Academy of Sciences

抄録

A novel organically templated layered cerium phosphate fluoride [(CH<SUB>2</SUB>)<SUB>2</SUB>(NH<SUB>3</SUB>)<SUB>2</SUB>]<SUB>0.5</SUB>[Ce<SUP>IV</SUP>F<SUB>3</SUB>(HPO<SUB>4</SUB>)] has been synthesized by hydrothermal synthesis technology, and characterized by means of single-crystal X-ray diffraction. Its unique layered structure is based on a network of novel CeO<SUB>3</SUB>F<SUB>5</SUB> polyhedral and PO<SUB>4</SUB> tetrahedral. The [NH<SUB>3</SUB>(CH<SUB>2</SUB>)<SUB>2</SUB>NH<SUB>3</SUB>]<SUP>+</SUP> cations contact with the adjacent layers via hydrogen bonds to compensate the negative charge of the inorganic framework.

収録刊行物

  • Chemistry letters

    Chemistry letters 33(4), 458-459, 2004-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10012847423
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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