Synthesis of Sequential Wholly Aromatic Polyketone Composed of 2,2′-Dimethoxybiphenylene Unit

  • Yonezawa Noriyuki
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Kameda Asami
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Jobashi Takashi
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Maruyama Satoshi
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology
  • Maeyama Katsuya
    Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture and Technology

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タイトル別名
  • Synthesis of Sequential Wholly Aromatic Polyketone Composed of 2,2'-Dimethoxybiphenylene Unit

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抄録

Sequential wholly aromatic polyketone 5, where 2,2′-dimethoxybiphenylene units and m,p-diphenylenedicarbonyl ones align alternately, was successfully synthesized via finely tuned designings of the structure and synthetic protocol for arenecarboxylic acid monomer (6). Different from the 2,2′-dimethoxybiphenylene-containing wholly aromatic polyketones (14) reported recently, the polyketone (5), the conjugated macromolecule composed of regiochemically sequenced arene and carbonyl moieties, is soluble in organic solvents.

収録刊行物

  • Polymer Journal

    Polymer Journal 36 (4), 345-351, 2004

    The Society of Polymer Science, Japan

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