Glass Forming Ability and Mechanical Properties of Misch Metal-Based Bulk Metallic Glass Matrix Composite

  • Kim Ji-Hun
    Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University
  • Lee Joo Yun
    Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University
  • Park Jin Man
    Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University
  • Fleury Eric
    Advanced Metals Research Center, Korea Institute of Science and Technology
  • Kim Won Tae
    Applied Science Division, Chongju University
  • Kim Do Hyang
    Center for Non-crystalline Materials, Department of Metallurgical Engineering, Yonsei University

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The effect of replacement of lanthanide by misch metal (Mm) in La-Al-TM (TM; transition metal, Ni, Cu and Co) alloys has been investigated to evaluate the possibility of fabrication of in-situ glass matrix composites with enhanced properties. For the as-cast cylindrical Mm55Al25Ni10Cu10 alloy ingot with 3 mm diameter, the microstructure is consisted of two kinds of a few μm size crystalline phases (volume fraction: 4.6%) uniformly distributed in the metallic glass matrix. The substitution of La by Mm reduces the glass forming ability (GFA), i.e., lower the reduced glass transition temperature, Trg (= Tg/TL, where TL is the liquidus temperature) and smaller superliquid temperature region, ΔTx (= Tx - Tg, where, Tg is the glass transition temperature and Tx the onset temperatures of crystallization), enabling the fabrication of in-situ BMG matrix composite. The Mm55Al25Ni10Cu10 metallic glass matrix composite sample exhibits the compressive fracture strength of 931 MPa, and in particular enhanced the compressive plastic strain of 1.2% before failure. The enhanced strength and ductility was explained by the presence of fine crystalline phases embedded in the BMG matrix, which led to a multiple shear band formation.

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