Palladium-Catalyzed Elimination Reaction of Acyclic (<i>E</i>)-Allylic Acetates: The Stereochemistry Elucidated by “<i>Syn</i>-Effect”
-
- Hiroyuki Takenaka
- Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
-
- Yutaka Ukaji
- Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
-
- Katsuhiko Inomata
- Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
この論文をさがす
抄録
<jats:title>Abstract</jats:title> <jats:p>The stereochemistry of the elimination reaction of acyclic (E)-allylic acetates into the corresponding 1,3-dienes catalyzed by palladium in the presence of a base was investigated. The Z/E ratios of the resulting 1,3-dienes varied with the δ-substituents of the starting allylic acetates. This phenomenon was discussed based on the concept of a “syn-effect,” which is most primarily rationalized by a σ → π* interaction.</jats:p>
収録刊行物
-
- Chemistry Letters
-
Chemistry Letters 34 (2), 256-257, 2005-01-22
Oxford University Press (OUP)
- Tweet
キーワード
詳細情報
-
- CRID
- 1360565169064063616
-
- NII論文ID
- 10014364629
-
- NII書誌ID
- AA00603318
-
- ISSN
- 13480715
- 03667022
-
- データソース種別
-
- Crossref
- CiNii Articles
- KAKEN