日進月歩パラジウム触媒の化学：こんな反応がパラジウム触媒で

• 辻 二郎

  東京工業大学

書誌事項

タイトル別名

• Rapid Progress in Palladium-catalyzed Reactions: Novel Palladium-catalyzed Reactions Recently Discovered
• ラウンジ ニッシンゲッポ パラジウム ショクバイ ノ カガク コンナ ハンノウ ガ パラジウム ショクバイ デ
• Novel Palladium-catalyzed Reactions Recently Discovered
• こんな反応がパラジウム触媒で

抄録

New palladium-catalyzed reactions recently discovered which involve β-carbon elimination and formation of palladacycles as key reactions are surveyed. Arylation of aromatic ring takes place by the reaction of α, α-disubstituted arylmethanols with aryl halides via β-carbon elimination. Novel methods of functionalization of aromatics were discovered by Catellani by the unique palladium and norbornene-catalyzed coupling reactions of aryl halides. Polyarylations of phenols and other aromatic rings with aryl halides proceed smoothly via facile formation of palladacycles due to the participation of OH groups. These reactions proceed via the following interconversion between Pd(0)-Pd(II)-Pd(IV) species.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 63 (5), 539-550, 2005

  公益社団法人 有機合成化学協会

キーワード

• β-carbon elimination
• palladacycle
• norbornene-catalyzed reactions
• arylation of aromatic compounds
• Pd(IV) species
• cyclopalladation
• 2-arylation of phenols

詳細情報

• CRID: 1390282680289600768
• NII論文ID: 10015727646
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.63.539
• COI: 1:CAS:528:DC%2BD2MXktlCqu7c%3D
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 7362479
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7362479
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可