Hybrid Organic-Inorganic Conductor Coupled with BEDT-TTF and Photochromic Nitrosyl Ruthenium Complex

• Masashi Okubo

• Masaya Enomoto

• Kazuko Koyama

書誌事項

タイトル別名

• Hybrid Organic Inorganic Conductor Coupled with BEDT TTF and Photochromic Nitrosyl Ruthenium Complex

抄録

An organic–inorganic hybrid system coupled with an organic conductor and photosensitive transition metal complex has a possibility to exhibit fascinating multifunctionalities, such as photo-controllable conductor. To explore multifunctional materials, such as a photo-tunable conductor, we prepared (BEDT-TTF)4[RuCl5(NO)]·C6H5CN (BEDT-TTF: 4,5-bis(ethylenedithio)tetrathiafulvalene) by electrocrystallization, and investigated the structural and physical properties. X-ray crystallographic analysis shows alternate layers of BEDT-TTF cations and ruthenium complex anions. The organic layer is formed by the dimers of BEDT-TTF arranged almost perpendicular to each other, which indicates that the donor arrangement of this salt belongs to κ-type. Based on the Raman spectrum, the oxidation state of the BEDT-TTF molecules is estimated to be +0.7. X-ray structural analysis and the EPR spectra suggest that there is a partial electron transfer from BEDT-TTF to the π* orbital of NO ligand in [RuCl5(NO)] through a short intermolecular contact. A magnetic susceptibility measurement and the EPR spectra proved this compound to be a localized spin system due to a strong on-site Coulomb repulsion, which results in the semiconducting behavior of this compound.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 78 (6), 1054-1060, 2005

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1523951028224625664
• NII論文ID: 10016143177
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.78.1054
• NDL書誌ID: 7331422
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7331422
• Web Site: https://academic.oup.com/bcsj/article-pdf/78/6/1054/56267226/bcsj.78.1054.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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