Liquid-Solid Interface Free Energies for Metals from Free-volume Method and Interface Structural Model

• Nakajima Keiji

  Division of Applied Process Metallurgy, Department of Materials Science and Engineering, Royal Institute of Technology (KTH) Corporate Research & Development Laboratories, Sumitomo Metal Industries, Ltd.

Abstract

The thermodynamic approximate-expression for liquid–solid interface free energy which has its origin in the loss of configurational entropy due to the adjustment of the liquid to a boundary was derived. Triangular-square-pentagonal lattices were proposed for a structural model of the liquid–solid interface. Calculated values from the thermodynamic approximate-expression and the interface structural model showed a fair agreement with previous experimental data.

Journal

• ISIJ International

  ISIJ International 46 (6), 795-800, 2006

  The Iron and Steel Institute of Japan

Keywords

• liquid–solid interface free energy
• metal
• free-volume method
• triangular-square-pentagonal lattice
• homogeneous nucleation

Details

• CRID: 1390001206487204224
• NII Article ID: 10018046900
• NII Book ID: AA10680712
• DOI: 10.2355/isijinternational.46.795
• COI: 1:CAS:528:DC%2BD28XmtlOlsLo%3D
• ISSN: 13475460
• ISSN: 09151559
• Web Site: http://www.jstage.jst.go.jp/article/isijinternational/46/6/46_6_795/_pdf
• Text Lang: en
• Data Source:
  • JaLC
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed