Isolation and Characterization of an Allenylthioketene and 4-Methylenecyclobutenethiones Generated by Thermal Reaction of Alkynyl Propargyl Sulfides

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著者

    • AOYAGI Shigenobu
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • SUGIMURA Katsuaki
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • KANNO Nobuya
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • WATANABE Dai
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • SHIMADA Kazuaki
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University
    • TAKIKAWA Yuji
    • Department of Chemical Engineering, Faculty of Engineering, Iwate University

抄録

Alkynyl propargyl sulfides underwent [3,3] sigmatropic rearrangement followed by ring closure to afford isolable 4-methylenecyclobutenethiones, and an intermediary allenylthioketene <B>2</B> was isolated by heating <I>t</I>-butyldimethylsilylethynyl propargyl sulfide.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(9), 992-993, 2006-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018062805
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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