A Novel Organic–Inorganic Hybrid Based on Tungstoantimonate: Synthesis, Crystal Structure, and Properties of Na[{Cu(2,2′-bpy)(H2O)}2{Cu(2,2′-bpy)}2(<i>B</i>-α-SbW9O33)]·2H2O

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  • Jingping Wang
    Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University
  • Pengtao Ma
    Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University
  • Jie Li
    Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University
  • Jingyang Niu
    Institute of Molecular and Crystal Engineering, School of Chemistry and Chemical Engineering, Henan University

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<jats:title>Abstract</jats:title> <jats:p>A novel organic–inorganic hybrid tungstoantimonate Na[{Cu(2,2′-bpy)(H2O)}2{Cu(2,2′-bpy)}2(B-α-SbW9O33)]·2H2O (2,2′-bpy = 2,2′-bipyridine) was synthesized hydrothermally and characterized by elemental analyses, IR, EPR, TG, and X-ray single-crystal diffraction, whose polyoxoanion consists of two [Cu(2,2′-bpy)]2+ and two [Cu(2,2′-bpy)(H2O)]2+ complex groups grafted on a trivacant polyoxoanion B-α-[SbW9O33]9− skeleton.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 35 (9), 994-995, 2006-07-29

    Oxford University Press (OUP)

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