Nonfluorous, Highly CO_2-soluble Chelating Ligands for scCO_2 Metal Ion Extraction

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著者

    • YANG Hai-Jian
    • Key Laboratory for Analytical Chemistry of the State Ethnic Affairs Commission, College of Chemistry and Materials Science, South-Central University for Nationalities

抄録

A series of new nonfluorous chelating ligands derived from glucose have been designed and synthesized. All compounds are highly soluble in liquid or supercritical carbon dioxide. Solubility trend of these chelating compounds would be rationalized by the inductive effect of substituent on the benzene ring and the easy accessibility of benzylic ether oxygen and neighboring hydrogens. Preliminary metal ion extraction efficiency test showed that all our compounds are selective for Sr<SUP>2+</SUP> and Pb<SUP>2+</SUP> extraction.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(9), 1000-1001, 2006-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018062871
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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