Short Synthetic Route toward the Tricyclic Core of Schulzeines

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The tricyclic core of marine natural products schulzeines was synthesized using <I>N</I>-acyliminium ion cyclization. The intermediate <I>N</I>-acyliminium ion was generated from treatment of α-hydroxy-δ-lactam with a Lewis acid. The tricyclic products were obtained as a mixture of 2 diastereomers at the C-11b stereocenter. The diastereomeric ratios were low and dependent on the Lewis acid used in the reaction.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(9), 1008-1009, 2006-09-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018062945
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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