バリア放電によるベンゼンの分解 : 微量の酸素を含むアルゴン中での反応過程の検討 C_6H_6 Decomposition Using Barrier Discharge : Estimation of Reaction Processes in Ar at Low O_2 Concentrations

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The C<sub>6</sub>H<sub>6</sub> decomposition at atmospheric pressure is investigated using a barrier discharge in Ar at less than 4% O<sub>2</sub>. C<sub>6</sub>H<sub>6</sub> in the presence of O<sub>2</sub> in Ar is decomposed to CO, CO<sub>2</sub>, H<sub>2</sub>O, and HCOOH. Concentrations of these products are shown versus the concentration of C<sub>6</sub>H<sub>6</sub> decomposed with different amounts of electrical inputs, flow rates, and initial C<sub>6</sub>H<sub>6</sub> concentrations. At 4% O<sub>2</sub>, concentrations of CO and HCOOH are proportional to the concentration of C<sub>6</sub>H<sub>6</sub> decomposed. The concentrations of CO<sub>2</sub> and H<sub>2</sub>O increase with increasing concentration of C<sub>6</sub>H<sub>6</sub> decomposed at flow rate of 1000mL/min. However, at flow rates of 200mL/min and 500mL/min, the concentrations of CO<sub>2</sub> and H<sub>2</sub>O do not increase with increasing concentration of C<sub>6</sub>H<sub>6</sub> decomposed. As results of considering the dependence of the concentration of products and a simple calculation for chemical reactions, the concentration of O atoms produced by the discharge determines not the concentration of C<sub>6</sub>H<sub>6</sub> decomposed but the concentrations of products.

収録刊行物

  • 電気学会論文誌. A, 基礎・材料・共通部門誌 = The transactions of the Institute of Electrical Engineers of Japan. A, A publication of Fundamentals and Materials Society  

    電気学会論文誌. A, 基礎・材料・共通部門誌 = The transactions of the Institute of Electrical Engineers of Japan. A, A publication of Fundamentals and Materials Society 126(5), 321-327, 2006-05-01 

    The Institute of Electrical Engineers of Japan

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各種コード

  • NII論文ID(NAID)
    10018111095
  • NII書誌ID(NCID)
    AN10136312
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    03854205
  • NDL 記事登録ID
    7946682
  • NDL 雑誌分類
    ZN31(科学技術--電気工学・電気機械工業)
  • NDL 請求記号
    Z16-793
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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