Effect of Intramonolayer Hydrogen Bonding of Carboxyl Groups in Self-assembled Monolayers on a Single Force with Phenylurea on an AFM Probe Tip

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The molecular interaction force of the intermonolayer hydrogen bonding between phenylurea groups on a probe tip and carboxyl groups in self-assembled monolayers was measured directly by means of atomic force microscopy in ethanol. Gold-coated AFM probe tips were modified chemically with 2-(<i>N</i>′-phenylureido)ethanethiol possessing a terminal urea moiety, which is a well-known powerful functionality for forming stable hydrogen bondings with neutral and anionic species. Adhesion force measurements were carried out on gold substrates coated with a COOH-terminated SAM composed of 6-mercaptohexanoic acid in ethanol using the phenylurea-functionalized probe tip. The adhesion force observed was decreased in the presence of H<sub>2</sub>PO<sub>4</sub><sup>-</sup> in the measurement bath, indicating that the intermonolayer hydrogen bonding between the phenylurea moieties and carboxyl groups attached covalently to the probe tip and substrate, respectively, is suppressed by the anion added to the measurement solution. The specific hydrogen-bonding force was measured on binary mixed SAMs prepared by mixing 6-mercaptohexanoic acid with 1-hexanethiol. The individual hydrogen-bonding force between the phenylurea-modified tip and the binary mixed SAMs with various fractions of MHA was evaluated by repetitive force measurements and their statistical analyses by an autocorrelation method. We discuss the effect of diluting the COOH-terminated component in the mixed SAM on the adhesion force and the single force between the phenylurea and carboxyl groups in terms of competition between intermonolayer and intramonolayer hydrogen bonding.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 22(4), 521-527, 2006-04-10

    The Japan Society for Analytical Chemistry

参考文献:  67件中 1-67件 を表示

  • <no title>

    HEINZ W. F.

    Nanotechnology 17, 143, 1999

    被引用文献1件

  • <no title>

    ULMAN A.

    An Introduction to Ultrathin Organic Films : From Lagngmuir-Blodgett to Self-Assembly, 1991

    被引用文献1件

  • <no title>

    HAN T.

    Anal. Chim. Acta 307, 365, 1995

    被引用文献1件

  • <no title>

    ZHANG J.

    Anal. Chem. 72, 1973, 2000

    被引用文献1件

  • <no title>

    FLORIN E.-L.

    Science 264, 415, 1994

    被引用文献1件

  • <no title>

    LO Y.-S.

    Langmuir 15, 1373, 1999

    被引用文献1件

  • <no title>

    LO Y.-S.

    Langmuir 17, 3741, 2001

    被引用文献1件

  • <no title>

    RIGBY-SINGLETON S. M.

    J. Chem. Soc., Perkin Trans. 2, 2002

    被引用文献1件

  • <no title>

    AULETTA T.

    J. Am. Chem. Soc. 126, 1577, 2004

    被引用文献1件

  • <no title>

    GIL R.

    Chem. Commun., 2003

    被引用文献1件

  • <no title>

    KADO S.

    Chem. Lett., 2001

    被引用文献1件

  • <no title>

    KADO S.

    J. Am. Chem. Soc. 127, 3026, 2005

    被引用文献1件

  • <no title>

    CROOKS R. M.

    Spectroscopy 8, 28, 1993

    被引用文献1件

  • <no title>

    KIM K.

    J. Electroanal. Chem. 512, 83, 2001

    被引用文献1件

  • <no title>

    DE LOOS M.

    Eur. J. Org. Chem., 2000

    被引用文献1件

  • <no title>

    NISHIZAWA S.

    Anal. Sci. 14, 595, 1998

    被引用文献1件

  • <no title>

    ALONSO B.

    Chem. Commun., 2002

    被引用文献1件

  • <no title>

    SASAKI S.

    J. Chem. Soc., Perkin. Trans. 2, 2001

    被引用文献1件

  • <no title>

    SISSON A. L.

    Chem. Commun., 2003

    被引用文献1件

  • <no title>

    JAGESSAR R. C.

    Chem. Commun., 1997

    被引用文献1件

  • <no title>

    NISSINK J. W. M.

    J. Chem. Soc., Perkin Trans. 2, 1998

    被引用文献1件

  • <no title>

    VAZQUEZ M.

    Angew. Chem. Int. Ed. 43, 1962, 2004

    被引用文献1件

  • <no title>

    VARGHESE R.

    Chem. Commun., 2005

    被引用文献1件

  • <no title>

    STEPHAN H.

    Chem. Commun., 1999

    被引用文献1件

  • <no title>

    HUH S.

    Angew. Chem. Int. Ed. 44, 1826, 2005

    被引用文献1件

  • <no title>

    TAKANO H.

    Chem. Rev. 99, 2845, 1999

    被引用文献3件

  • <no title>

    SAMORI B.

    Chem. Eur. J. 6, 4249, 2000

    被引用文献2件

  • <no title>

    JANSHOFF A.

    Angew. Chem. Int. Ed. 39, 3212, 2000

    被引用文献5件

  • <no title>

    HUGEL T.

    Macromol. Rapid Commun. 22, 989, 2001

    被引用文献6件

  • <no title>

    ULMAN A.

    Chem. Rev. 96, 1533-1554, 1996

    被引用文献64件

  • <no title>

    FRISBIE C. D.

    Science 265, 2071, 1994

    DOI 被引用文献38件

  • <no title>

    NOY A.

    J. Am. Chem. Soc. 117, 7943, 1995

    被引用文献6件

  • <no title>

    VESENOV DV

    J. Am. Chem. Soc. 119, 2006, 1997

    被引用文献3件

  • <no title>

    VAN DER VEGTE E. W.

    J. Phys. Chem. B 101, 9563, 1997

    被引用文献3件

  • <no title>

    VAN DER VEGTE E. W.

    Langmuir 13, 4357, 1997

    被引用文献2件

  • <no title>

    NOY A.

    Langmuir 14, 1508, 1998

    被引用文献2件

  • <no title>

    SINNIAH S. K.

    J. Am. Chem. Soc. 118, 8925, 1996

    被引用文献2件

  • <no title>

    ITO T.

    Langmuir 13, 4323, 1997

    被引用文献2件

  • <no title>

    ITO T.

    Langmuir 15, 2788, 1999

    被引用文献2件

  • <no title>

    SMITH D. A.

    J. Phys. Chem. B 104, 8862, 2000

    被引用文献3件

  • <no title>

    LEE G. U.

    Langmuir 10, 354, 1994

    被引用文献6件

  • <no title>

    LEE G. U.

    Science 266, 771, 1994

    被引用文献14件

  • <no title>

    BOLAND T.

    Proc. Natl. Acad. Sci. U. S. A. 92, 5297, 1995

    被引用文献4件

  • <no title>

    WENZLER L. A.

    Langmuir 13, 3761, 1997

    被引用文献2件

  • <no title>

    WENZLER L. A.

    Anal. Chem. 69, 2855, 1997

    被引用文献2件

  • <no title>

    CONTI M.

    Angew. Chem. Int. Ed. 39, 215, 2000

    被引用文献2件

  • <no title>

    TROMAS C.

    Angew. Chem. Int. Ed. 40, 3052, 2001

    被引用文献6件

  • <no title>

    SCHONHERR H.

    J. Am. Chem. Soc. 122, 4963, 2000

    被引用文献3件

  • <no title>

    ZAPOTOCZNY S.

    Langmuir 18, 6988, 2002

    被引用文献4件

  • <no title>

    SKULASON H.

    J. Am. Chem. Soc. 124, 15125, 2002

    被引用文献3件

  • <no title>

    KADO S.

    J. Am. Chem. Soc. 125, 4560, 2003

    被引用文献4件

  • <no title>

    CROOKS R. M.

    Faraday Discuss. 107, 285, 1997

    DOI 被引用文献1件

  • <no title>

    ZHAO J.

    Electroanalysis 11, 1108, 1999

    被引用文献1件

  • <no title>

    AOKI K.

    J. Electroanal. Chem. 478, 101, 1999

    被引用文献1件

  • <no title>

    GERSHEVITZ O.

    J. Am. Chem. Soc. 126, 482, 2004

    DOI 被引用文献1件

  • <no title>

    CREAGER S. E.

    Langmuir 10, 3675, 1994

    被引用文献2件

  • <no title>

    VAN ESCH J.

    Chem. Eur. J. 5, 937, 1999

    被引用文献2件

  • <no title>

    SCHOONBEEK F. S.

    Chem. Eur. J. 6, 2633, 2000

    被引用文献4件

  • <no title>

    MOHMEYER N.

    Chem. Eur. J. 11, 863, 2005

    DOI 被引用文献1件

  • <no title>

    BEER P. D.

    Angew. Chem., Int. Ed. Engl. 40, 486-516, 2001

    被引用文献17件

  • <no title>

    JEONG H.

    Bull. Korean. Chem. Soc. 20, 1232, 1999

    被引用文献1件

  • <no title>

    HAYASHIDA O.

    Angew. Chem. Int. Ed. 41, 3423, 2002

    被引用文献3件

  • <no title>

    BAIN CD

    J. Am. Chem. Soc. 111, 321, 1989

    DOI 被引用文献22件

  • <no title>

    NISHIZAWA M.

    J. Electroanal. Chem. 436, 213, 1997

    被引用文献1件

  • <no title>

    KAKIUCHI T.

    Langmuir 17, 1599, 2001

    被引用文献5件

  • <no title>

    FOLKERS J. P.

    Langmuir 8, 1330, 1992

    被引用文献3件

各種コード

  • NII論文ID(NAID)
    10018123634
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    7871882
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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