固体酸・固体塩基を用いる環境調和型有機電解合成 Environmentally Friendly Electroorganic Synthesis Using Solid-Supported Acids and Bases

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著者

    • 田嶋 稔樹 TAJIMA Toshiki
    • 東京工業大学大学院総合理工学研究科物質電子化学専攻 Department of Electronic Chemistry, Tokyo Institute of Technology
    • 淵上 寿雄 FUCHIGAMI Toshio
    • 東京工業大学大学院総合理工学研究科物質電子化学専攻 Department of Electronic Chemistry, Tokyo Institute of Technology

抄録

We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 64(4), 406-414, 2006-04-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10018131755
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    7921791
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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