固体酸・固体塩基を用いる環境調和型有機電解合成 [in Japanese] Environmentally Friendly Electroorganic Synthesis Using Solid-Supported Acids and Bases [in Japanese]
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We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.
- J. Synth. Org. Chem. Jpn.
J. Synth. Org. Chem. Jpn. 64(4), 406-414, 2006-04-01
The Society of Synthetic Organic Chemistry, Japan