Environmentally Friendly Electroorganic Synthesis Using Solid-Supported Acids and Bases

• Tajima Toshiki

  Department of Electronic Chemistry, Tokyo Institute of Technology

• Fuchigami Toshio

  Department of Electronic Chemistry, Tokyo Institute of Technology

Bibliographic Information

Other Title

• 固体酸・固体塩基を用いる環境調和型有機電解合成
• コタイ サン コタイ エンキ オ モチイル カンキョウ チョウワガタ ユウキ デンカイ ゴウセイ

Abstract

We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

Journal

• Journal of Synthetic Organic Chemistry, Japan

  Journal of Synthetic Organic Chemistry, Japan 64 (4), 406-414, 2006

  The Society of Synthetic Organic Chemistry, Japan

Keywords

• green sustainable chemistry
• solid-supported acid
• solid-supported base
• anodic fluorination
• potassium fluoride
• anodic methoxylation
• anodic acetoxylation
• Kolbe electrolysis
• non-Kolbe electrolysis
• supporting electrolyte

Details

• CRID: 1390001205311033088
• NII Article ID: 10018131755
• NII Book ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.64.406
• ISSN: 18836526
• ISSN: 00379980
• NDL BIB ID: 7921791
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I7921791
• Text Lang: ja
• Data Source:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• Abstract License Flag: Disallowed