Electric Characteristics of Thin SiO2 Film Embedded with Ge Nanoparticles Formed by Negative Ion Implantation

  • ARAI Nobutoshi
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University Advanced Technology Research Laboratories, SHARP Corporation
  • TSUJI Hiroshi
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • GOTOH Naoyuki
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • MINOTANI Takashi
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • NAKATSUKA Hiroyuki
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • KOJIMA Kenji
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • YANAGITANI Toshio
    Advanced Technology Research Laboratories, SHARP Corporation
  • OKUMINE Tetsuya
    Advanced Technology Research Laboratories, SHARP Corporation
  • OHNISHI Hitoshi
    Advanced Technology Research Laboratories, SHARP Corporation
  • SATOH Takeshi
    Advanced Technology Research Laboratories, SHARP Corporation
  • HARADA Masatomi
    Advanced Technology Research Laboratories, SHARP Corporation
  • ADACHI Kouichirou
    Advanced Technology Research Laboratories, SHARP Corporation
  • KOTAKI Hiroshi
    Advanced Technology Research Laboratories, SHARP Corporation
  • GOTOH Yasuhito
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University
  • ISHIKAWA Junzo
    Department of Electronic Science and Engineering, Graduate School of Engineering, Kyoto University

Bibliographic Information

Other Title
  • 負イオン注入形成Geナノ粒子含有SiO2薄膜の電気的特性
  • フイオン チュウニュウ ケイセイ Ge ナノ リュウシ ガンユウ SiO2 ハクマク ノ デンキテキ トクセイ

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Abstract

  Electric characteristics of 25-nm-SiO2/Si films embedded with Ge nanoparticles were investigated by CV method. Ge nanoparticles were formed by negative ion implantation and subsequent thermal annealing. Ge atoms in the SiO2 were evaluated by high-resolution RBS and cross-sectional TEM. Ge atoms were implanted at 10 keV with 1×1015 and 5×1015 ions/cm2. The samples were annealed at 300, 500, 700 and 900°C for 1 h. After annealing at 900°C, Ge atoms diffused down to SiO2/Si interface, so the sample could not be evaluated by CV method. After annealing at 300°C, the voltage shift in the hysteresis of a CV curve was very small, so it could not be applied to the memory devices. While after annealing at 500°C, the voltage shifts of both samples implanted with doses of 1×1015 and 5×1015 ions/cm2 were wide. Calculations of charge and nanoparticle intensity from flat band shift and from implanted Ge dose show that each nanoparticle with about 3-nm diameter has only one electron. These results suggest that thin SiO2 films embedded with Ge nanoparticles formed with negative ion implantation can be applied to the memory devices.<br>

Journal

  • Shinku

    Shinku 49 (3), 180-182, 2006

    The Vacuum Society of Japan

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