Amination of the Ortho C-H Bonds by the Cu(OAc)_2-mediated Reaction of 2-Phenylpyridines with Anilines

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著者

    • UEMURA Takeshi
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • IMOTO Shinya
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University
    • CHATANI Naoto
    • Department of Applied Chemistry, Faculty of Engineering, Osaka University

抄録

The reaction of 2-phenylpyridines with anilines in the presence of Cu(OAc)<SUB>2</SUB> as a promoter results in selective mono-amination of the ortho C–H bonds in 2-phenylpyridines to give amine derivatives in high yields per the conversion. This is the rare example of the functionalization of C–H bonds to C–N bonds.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(8), 842-843, 2006-08-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018187232
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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