Formation of a Stable Sulfenic Acid by Hydrolysis of a Thionitrate and a Sulfenyl Bromide

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著者

    • GOTO Kei
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • SHIMADA Keiichi
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • FURUKAWA Shunsuke
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • MIYASAKA Shinji
    • Department of Chemistry, Graduate School of Science, The University of Tokyo
    • TAKAHASHI Yusuke
    • Department of Chemistry, Graduate School of Science, The University of Tokyo

抄録

Alkaline hydrolysis of a thionitrate and a sulfenyl bromide bearing a bowl-type steric protection group produced a stable sulfenic acid. This provides a conclusive demonstration of these elementary processes. It was shown that a very efficient steric protection group is necessary to prevent the condensation of the sulfenate anion generated during the hydrolysis.

収録刊行物

  • Chemistry letters  

    Chemistry letters 35(8), 862-863, 2006-08-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018187382
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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