A Novel Recovery Method for Treating Wastewater Containing Fluoride and Fluoroboric Acid
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- Itakura Takeshi
- Department of Applied Chemistry, Graduate School of Engineering, Nagoya University
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- Sasai Ryo
- Division of Environmental Research, EcoTopia Science Institute, Nagoya University
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- Itoh Hideaki
- Division of Environmental Research, EcoTopia Science Institute, Nagoya University
書誌事項
- タイトル別名
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- Novel Recovery Method for Treating Wastewater Containing Fluoride and Fluoroboric Acid
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抄録
A new treatment method for wastewater containing concentrated fluoride and fluoroborate ions by hydrothermal treatment were developed. The treatment is an earth-mimetic method to produce natural minerals by hydrothermal treatment with Ca(OH)2 as a mineralizer. Results of various analyses of the precipitate indicated that the recovered minerals were Ca2B2O5·H2O (parasibirskite) and CaF2 (fluorite). By optimizing the conditions, it was possible to recover more than 98 percent of the boron and 99.9 percent of the fluorine from model wastewater samples containing fluoride (7000 mg L−1) and fluoroborate (8000 mg L−1) ions. Moreover, in the case of fluoroborate ions, the present treatment simultaneously caused the decomposition of the fluoroborate ion, the formation of each minerals, and the preventation of redissolution of parasibirskite. Therefore, the present hydrothermal mineralization treatment with the Ca(OH)2 mineralizer is an effective technique to recover boron and fluorine from wastewater.
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 79 (8), 1303-1307, 2006
公益社団法人 日本化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204143887872
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- NII論文ID
- 130004058742
- 10018211285
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- NII書誌ID
- AA00580132
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- ISSN
- 13480634
- 00092673
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- NDL書誌ID
- 8010131
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可